VALVOLINE CO -- PYROIL CARB CLEANER (BONUS) 12/15.6 OZ  -- 6850-00N074547
<pre>=====================  Product Identification  =====================

Product ID:PYROIL CARB CLEANER (BONUS) 12/15.6 OZ
MSDS Date:07/14/1995
FSC:6850
NIIN:00N074547
=== Responsible Party ===
Company Name:VALVOLINE CO
Address:3499 DABNEY DR
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Info Phone Num:606-357-7847
Emergency Phone Num:800-274-5263
CAGE:IO754
=== Contractor Identification ===
Company Name:THE VALVOLINE CO
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7847
CAGE:IO754
Company Name:VALVOLINE OIL CO
Address:3499 BLAZER PKY
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7206 / 800-274-5263
CAGE:72527

=============  Composition/Information on Ingredients  =============

Ingred Name:XYLENE (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 39%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 26%
OSHA PEL:200 PPM, S
ACGIH TLV:200PPM/250STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 20-30%
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 4.5-15%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT

Ingred Name:ETHYL BENZENE (SARA 313)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 6.9-7.7%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/125STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:VOLATILE ORGANIC COMPOUND: 99.770%; 604.000 G/L (5.040
    LBS/GAL)
RTECS #:9999999VO
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:EFTS OF OVEREXP: THE FOLLOWING EFTS IN LAB ANIMALS: LIVER
    ABNORM; ANEMIA; SPLEEN, NERV SYS, EYE, KIDNEY, LUNG & (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: BRAIN DMG. OVEREXP MAY CAUSE THE FOLLOWING EFTS IN
    HUMANS: LIVER ABNORM, EYE DMG. TOLUENE MAY BE HARMFUL (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: TO FETUS BASED ON LAB ANIMAL STUDIES. INTENTIONAL
    MISUSE BY DELIBERATE INHAL OF TOLUENE HAS BEEN ASSOC (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: W/LIVER, KIDNEY & BRAIN DMG IN HUMANS. RPTD EXPOS
    TO TOLUENE HAS BEEN ASSOC W/HIGH FREQUENCY HEARING (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: LOSS BASED ON EVIDENCE IN LAB ANIMALS; HUMAN HLTH
    CONSEQUENCES OF THIS FINDING IS UNCERTAIN. TOLUENE (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ LIST. SEEK
    CONSULT FROM APPROP HLTH PROFESSIONALS CONCERNING (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: LATEST HAZ LIST INFORMATION & SAFE HANDLING &
    EXPOSURE INFORMATION .
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: COMPLETED. STOP SPILL AT SOURCE. PVNT FROM
    ENTERING DRAINS, SEWERS, STREAMS/OTHER BODIES OF WATER. (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: PVNT FROM SPREADING. IF RUNOFF OCCURS, NOTIFY AUTH
    AS REQUIRED. PUMP/VACUUM TRANSFER SPILLED PROD TO (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: CLEAN CONTRS FOR RECOVERY. ABSORB UNRECOVERABLE
    PROD. TRANSFER CONTAM ABSORB, SOIL & OTHER MATLS TO (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: CONTRS FOR DISP. PVNT RUN-OFF TO SEWERS,
    STREAMS/OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS
    OCCURRED.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: ACIDOSIS, VISUAL DISTURB & BLINDNESS. SINCE
    METABOLISM IS REQUIRED FOR THESE TOX SYMPS, THEIR (ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: ONSET MAY BE DELAYED FROM 6-30 HRS FOLLOWING
    INGEST. ETHANOL COMPETES FOR SAME METABOLIC PATHWAY & HAS (ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21: BEEN USED TO PVNT METHANOL METABOLISM. ETHANOL
    ADMIN IS INDICATED IN SYMPTOMATIC PATIENTS/AT BLOOD (ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22: METHANOL CONCENTRATIONS ABOVE 20 UG/DL. METHANOL IS
    EFFECTIVELY REMOVED BY HEMODIALYSIS.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: IRRIT, STINGING, TEARING,
    REDNESS, SWELL & BLURRED VISION. SKIN: MILD IRRIT. PRLNG/RPTD EXPOS
    MAY DRY SKIN. REDNESS, BURNING, DRYING & CRACKING, & SKIN BURNS.
    INGEST: SINGLE DOSE ORAL TOX  IS LOW. INGEST SML AMTS DURING NORM
    HNDLG IS NOT LIKELY TO CAUSE HARMFUL EFTS; INGEST LGE AMTS MAY BE
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: HARMFUL. MATL CAN ENTER LUNGS DURING
    SWALLOWING/VOMIT & CAUSE LUNG INFLAMM &/DMG. INHAL: EXPOS TO
    VAP/MIST IS POSS. SYMPS OF EXPOS: GI IRRIT (NAUS, VOMIT, DIARR),
    IRRIT (NOSE, THROAT, RESP T RACT), CNS DEPRESS (DIZZ, DROW, WEAK,
    FATG, NAUS, HDCH, UNCON), & DEATH. TARGET ORGAN EFTS: OVEREXP MAY
    CAUSE (ING 8)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN DISORDERS, LUNG
    DISORDERS (E.G., ASTHMA-LIKE CONDITIONS); LIVER ABNORMALITIES;
    ANEMIA; SPLEEN, NERVOUS SYSTEM, EYE, KIDNEY, LUNG AND BRAIN DAMAGE.

=======================  First Aid Measures  =======================

First Aid:EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15 MIN. SEE MD .
    SKIN: FLUSH W/COPIOUS AMTS OF WATER. SEE MD . INHAL: REMOVE TO
    FRESH AIR. SUPPORT BRTHG (GIVE OXYGEN/ARTF RESP) . INGEST: CA LL MD
    IMMED . NOTE TO MD: CONTAINS METHANOL WHICH CAN CAUSE INTOXICATION
    & CNS DEPRESS. METHANOL IS METABOLIZED TO FORMIC ACID &
    FORMALDEHYDE. THESE METABOLITES CAN CAUSE METABOLIC (ING 20)

=====================  Fire Fighting Measures  =====================

Lower Limits:1.0%
Upper Limits:36.5%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:MATL IS HIGHLY VOLAT & READILY GIVES OFF
    VAPS WHICH MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY
    PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, (SUP DAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:SML SPILL: ABSORB LIQ ON VERMICULITE, FLOOR
    ABSORB/OTHER ABSORB MATL. LGE SPILL: ELIM ALL IGNIT SOURCES
    (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING
    PROT EQUIP SHOULD BE EXCLUDED FR OM AREA OF SPILL UNTIL CLEAN-UP
    HAS BEEN (ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:CONTRS MAY BE HAZ WHEN EMPTIED. SINCE
    EMPTIED CONTRS RETAIN PROD RESIDUES (VAP, LIQ, &/SOLID), ALL HAZ
    PREC GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS
    INCLUDING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDED AND/OR
    BONDED WHEN MATERIAL IS TRANSFERRED.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS
    EXCEEDED, A NIOSH APPRVD AIR SUPP RESP IS ADVISED IN ABSENCE OF
    PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH RESPS (NEG
    PRESS TYPE) UNDER SPECI FIED CNDTNS (CONSULT YOUR (SUP DAT)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
    EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
    ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: SMKNG, ELEC MOTORS, STATIC DISCHARGE/OTHER IGNIT SOURCES AT
    LOCATIONS DISTANT FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING
    TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDU E)
    CAN IGNITE EXPLO. RESP PROT: INDUS HYGIENIST).
    ENGINEERING/ADMINISTRATIVE CTLS SHOULD BE IMPLEMENTED TO REDUCE
    EXPOS.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:133F,56C
Vapor Pres:181.700
Vapor Density:>1 (AIR=1)
Spec Gravity:0.770
Appearance and Odor:LIQUID
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, OPEN FLAME, AND PROLONGED
    STORAGE AT ELEVATED TEMPERATURES.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
    MONOXIDE, VARIOUS HYDROCARBONS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
    LOCAL, STATE AND FEDERAL REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.